Chemicals

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Chemicals in flasks (including Ammonium hydroxide and Nitric acid) lit in different colours. Credit: Joe Sullivan.

Chemicals is a lecture on the general nature and specific characteristics of various natural and hominin-made substances. It is an offering from the school of chemistry.

Chemistry[edit]

Main sources: Chemicals/Chemistry and Chemistry

Def. a natural science that deals with the composition and constitution of substances and the changes that they undergo as a consequence of alterations in the constitution of their molecules is called chemistry.

Def. a science that deals with

  1. the identification of the substances of which matter is composed,
  2. the investigation of their properties and the ways in which they interact, combine, and change, and
  3. the use of these processes to form new substances

is called chemistry.

Def. "a science that deals with the composition, structure, and properties of substances and of the transformations that they undergo"[1] is called chemistry.

"Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties.[2][3] Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds.

Theoretical chemicals[edit]

Def. any specific [...] element or [...] compound or alloy is called a chemical.

Hydrogens[edit]

Main sources: Chemicals/Hydrogens and Hydrogens
The spectral series of hydrogen is displayed on a logarithmic scale. Credit: .
Electron transitions and their resulting wavelengths for hydrogen. Energy levels are not to scale. Credit: .
The spectrum shows the lines in the visible due to emission from elemental hydrogen. Credit:Teravolt.
Milky Way is viewed by H-Alpha Sky Survey. Credit: David Brown and Douglas Finkbeiner.

The emission spectrum of atomic hydrogen is divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to electrons moving between energy levels in the atom. The spectral series are important in astronomy for detecting the presence of hydrogen and calculating red shifts. The spectral lines of hydrogen correspond to particular jumps of the electron between energy levels. The simplest model of the hydrogen atom is given by the Bohr model. When an electron jumps from a higher energy to a lower, a photon of a specific wavelength is emitted.

The spectral lines are grouped into series according to n'. Lines are named sequentially starting from the longest wavelength/lowest frequency of the series, using Greek letters within each series. For example, the 2 → 1 line is called "Lyman-alpha" (Ly-α), while the 7 → 3 line is called "Paschen-delta" (Pa-δ). Some hydrogen spectral lines fall outside these series, such as the 21 cm line; these correspond to much rarer atomic events such as hyperfine transitions.[4] The fine structure also results in single spectral lines appearing as two or more closely grouped thinner lines, due to relativistic corrections.[5]

The energy differences between levels in the Bohr model, and hence the wavelengths of emitted/absorbed photons, is given by the Rydberg formula[6]:

where n is the initial energy level, n′ is the final energy level, and R is the Rydberg constant. Meaningful values are returned only when n is greater than n′ and the limit of one over infinity is taken to be zero.

The familiar red H-alpha [Hα 656 nm] spectral line of hydrogen gas, which is the transition from the shell n = 3 to the Balmer series shell n = 2, is one of the conspicuous colors of the universe. It contributes a bright red line to the spectra of emission or ionization nebula, like the Orion Nebula, which are often H II regions found in star forming regions. In true-color pictures, these nebula have a distinctly pink color from the combination of visible Balmer lines that hydrogen emits.

A hydrogen-alpha filter is an optical filter designed to transmit a narrow bandwidth of light generally centered on the H-alpha wavelength. They are characterized by a bandpass width that measures the width of the wavelength band that is transmitted.[7] These filters are manufactured by multiple (~50) layers of vacuum-deposited layers. These layers are selected to produce interference effects that filter out any wavelengths except at the requisite band.[8] Alternatively, an etalon may be used as the narrow band filter (in conjunction with a "blocking filter" or energy rejection filter) to pass only a narrow (<0.1 nm) range of wavelengths of light centred around the H-alpha emission line. The physics of the etalon and the dichroic interference filters are essentially the same (relying on constructive/destructive interference of light reflecting between surfaces), but the implementation is different (an interference filter relies on the interference of internal reflections). Due to the high velocities sometimes associated with features visible in H-alpha light (such as fast moving prominences and ejections), solar H-alpha etalons can often be tuned (by tilting or changing the temperature) to cope with the associated Doppler effect. The Balmer series of emission lines from hydrogen occur in the visible spectrum of the Sun at: 397, 410, 434, 486, and 656 nm.

Hydrogen has two emission lines that occur in an electron cyclotron resonance (ECR) heated plasmas at 397.007 nm of the Balmer series (Hε) and 434.05 nm Hγ.[9]

Heliums[edit]

Main sources: Chemicals/Heliums and Heliums
The spectrum shows the lines in the visible due to emission from elemental helium. Credit:Teravolt.
The container holds a small amount of liquid helium. Credit: Vuerqex.

"C. FRIEDLÄNDER and H. Kayser have independently claimed to have found helium in the [Earth's] atmosphere. On examination of some photographs of the spectrum of neon I have identified six of the principal lines of helium, which thus establishes beyond question the presence of this gas in the air. The amount present in the neon it is, of course, impossible to estimate, but the green line (wave-length 5016 [501.6 nm]) is the brightest, as would be expected from the low pressure of the helium in the neon."[10]

Liquid helium as shown on the right is just above absolute zero in temperature.

Helium is a colorless and inert gas.

Helium is a noble gas.

Lithiums[edit]

Main sources: Chemicals/Lithiums and Lithiums
This spectrograph shows the visual spectral lines of lithium. Credit: T c951.
Lithium remains chemically inert when immersed in oil. Credit: Tomihahndorf.{{free media}}

"[T]he standard solar models have enjoyed tremendous success recently in terms of agreement between the predicted outer structure and the results from helioseismology[, but] some observed properties of the Sun still defy explanation, such as the degree of Li depletion" [the "solar Li abundance is roughly a factor of 200 below the meteoritic abundance"].[11]

Berylliums[edit]

This spectrograph shows the visual spectral lines of beryllium. Credit: Penyulap.
Beryllium crystalline fragment is >99 % pure and >140 g. Credit: Alchemist-hp.{{free media}}

Beryllium has at least six emission/absorption lines across the red.

The emission and absorption spectra for beryllium contain lines in the blue.

Above is a light spectrum of the emission and absorption lines of neutral, atomic beryllium. Important for violet astronomy is the apparent absence of strong lines well within the violet range and one strong line on the fringe of the violet and blue portions of the visual spectrum.

"Good agreement is seen between the 14C (Fig. 8a) and 10Be (Fig. 8b) records, which confirms they are indeed measuring changes of the GCR flux, since their respective transport processes from the atmosphere to archive are completely different. After its formation, 14C is rapidly oxidised to 14CO2 and then enters the carbon cycle and may reach a tree-ring archive. On the other hand, 10Be attaches to aerosols and eventually settles as rain or snow, where it may become embedded in a stable ice-sheet archive. The correlation between high GCR flux and cold North Atlantic temperatures embraces the Little Ice Age, which is seen not as an isolated phenomenon but rather as the most recent of around ten such events during the Holocene. This suggests that the Sun may spend a substantial fraction of time in a magnetically-quiet state."[12]

Notation: let the symbol DPM represent Diesel vehicle exhaust Particulate Matter.

"Moreover DPM can bear metals like antimony, arsenic, beryllium, cadmium, chromium, copper, iron, lead, magnesium, manganese, nickel, vanadium and zinc ... the dominant group of particles had a diameter of 20 to 25 nm (at 900 rpm 50% load or 25 to 30 nm 100% load) for individual soot nodules."[13]

Borons[edit]

Main sources: Chemicals/Borons and Borons
This spectrograph shows the visual spectral lines of beryllium. Credit: Penyulap.
These polycrystalline chunks are rhombohedral β-boron, net 25.5 grams. Credit: James L Marshall.{{free media}}

Boron has a red line near the orange portion of the visual spectrum.

Above is a light spectrum of the emission and absorption lines of neutral, atomic boron. Important for violet astronomy is the two strong lines well within the violet range and one weaker line on the fringe of the violet and blue portions of the visual spectrum.

The emission and absorption spectra for boron contain lines on the border between violet and blue.

"The proton-proton chain, or hydrogen burning, is postulated by standard stellar theory as the principal mechanism of energy generation in the sun during the current stage of its evolution. The net result of this chain of nuclear reactions is conversion of four protons into helium-4, and the energy released is carried off by photons, positrons, and neutrinos."[14]

The "pH change for deep Pacific Ocean water associated with both the 3% increase in salinity resulting from the growth of the ice caps and the 700-m deepening of the lysocline9 are so small that they would lie within the uncertainty of pH reconstruction based on boron isotopes. If the glacial to Holocene drop in pH (0.3 units) suggested by the boron isotope measurements on benthic foraminifera was mainly accomplished by excess CaCO2 accumulation, then the alkalinity of deep Pacific water must have been ~10% higher during glacial time. As a result, the carbonate ion concentration of deep Pacific water during glacial time would have been ~100 µmol kg-1 higher than the present-day value, deepening the calcite saturation horizon by several kilometres."[15]

For the "reedmergnerite unit, BSi4O10 ... The spectra showed small amounts of it, and we saw no evidence of fragmentation (i.e., no corresponding smaller fragments that would appear to be constituents). Thus, it does not appear to be the dominant group in the glass network. ... The borate association remains dominant, however, even as we increase the soda content."[16]

Carbons[edit]

Main sources: Chemicals/Carbons and Carbons
The spectrum shows the lines in the visible due to emission from elemental carbon. Credit:Teravolt.
Diamond and graphite are shown side by side, where the scale is based on a rough approximation. Credit: Robert Lavinsky.{{free media}}

Carbon has an emission line in plasmas at 529.053 nm from C VI.[9]

"The [oxygen] green line occurs at 5577.339Å, in the middle of the strong C2 (1,2) band, and thus has seldom been observed."[17]

Carbon has one strong line in the red.

Carbon has three emission lines that occur in an electron cyclotron resonance (ECR) heated plasmas: 464.742, 465.025, and 465.147 nm from C III.[9]

Carbon has an emission line that occurs in plasmas at 449.881 nm from C VI.[9]

From the spectrum above, carbon has at least two lines in the violet.

"In general, during 1990-1991 most of the carbon biomass was contributed by diatoms, while during 1992-1993 it was contributed mainly by flagellates, although during Leg II of 1993 dinoflagellates were the dominant group in terms of carbon content."[18]

Nitrogens[edit]

Main sources: Chemicals/Nitrogens and Nitrogens
The spectrum shows the lines in the visible due to emission from elemental nitrogen. Credit:Kurgus.
Liquid nitrogen can be poured. Credit: Robin Müller.

On the right liquid nitrogen is shown being poured.

Molecular nitrogen (N2) is a colorless, odorless gas at room temperature.

"The disintegration of nitrogen by slow neutrons has been studied in photographic emulsions of different sensitivity, which enable an unambiguous distinction to be made between the emission of α-particles and protons. Evidence has been obtained that the disintegration takes place according to the reaction

1n + 14
7
N
14
5
B
+ 4
2
He

with a cross-section of about 10−24 cm2."[19]

"The fast neutrons from uranium fission can be moderated by elastic collision with graphite or heavy water in a nuclear reactor until their velocity is reduced to that of thermal energies (average 2200 meters/sec= 0.025 electron volts); such very slow neutrons are called thermal neutrons. Unlike fast neutrons, whose principal reaction with matter is one of scattering, thermal neutrons because of their very low energy and velocity are more likely to be captured than scattered by the atoms they encounter. Most of the reactions of biological elements with thermal neutrons are capture reactions. After an atom captures a neutron, it forms a new compound nucleus with an excess of energy. This new compound nucleus may then:

  1. emit immediately a capture radiation to form a radioactive daughter which subsequently emits beta or gamma rays at a rate characteristic for the isotope formed, e.g.,
14
7
N
+ 1n → [15
7
N
] → 14
6
C
* + p (half life = 6,000 years) → 14
7
N
+ β-."[20]

"Initially, the 14
C
atoms get oxidized to 14
CO
, primarily (Pandow et al. 1960; MacKay et al. (1963):"[21]

  1. C(g) + O2 ⟶ CO + O: ∆H = –138.96kcal

"In the atmosphere, initially 90–100% of the 14
C
produced is oxidized to 14
CO
(Pandow et al. 1960)."[21]

"In the atmosphere, the main removal process for 14
CO
is oxidation by OH radicals (cf. Jockel et al. 1999). Because of the low abundance of CO in the atmosphere, and the formation of 14
CO
initially, the 14
C
/12
C
ratio in the atmospheric CO is much higher than in the atmospheric CO
2
; by about two orders of magnitude in the lower stratosphere (Brenninkmeijer et al. 1995)."[21]

Oxygens[edit]

Main sources: Chemicals/Oxygens and Oxygens
The spectrum shows the lines in the visible due to emission from elemental oxygen. Credit:Teravolt.
This is a spectrum of Ring Nebula (M57) in range 450.0 — 672.0 nm. Credit: Minami Himemiya.
Liquid oxygen is the liquid in the ampoule that has a pale blue color. Credit: Vimal Cylinder Supplier.
Spectrum = gas discharge tube filled with oxygen O2, used with 1.8 kV, 18 mA, 35 kHz. ≈8" length. Credit: Alchemist-hp.
The surface of a MEMS device is cleaned with bright, blue oxygen plasma in a plasma etcher to rid it of carbon contaminants. (100mTorr, 50W RF) Credit: .

"[A]irglow emissions [have been] measured by using vertical-viewing photometers [for the] O(1S) green line at 557.7 nm [with a] background at 566 nm"[22].

The O III emission lines are at 495.9 and 500.7 nm.[23]

Oxygen has an emission line that occurs in plasmas at 527.62 nm from O IV.[9]

"Since the early work of Ångström,* we have the published records of over a hundred investigations on the spectrum, and many others on the origin or other phenomena characteristic of the aurora."[24] "Babcock, using a Fabry and Perot interferometer, determined very accurately the wave-length of the auroral green line 5577. ... After a careful examination of all the results obtained in these reports, we may only say that the exact nature of the cosmical rays, responsible for the aurora, remains a mystery. ... The origin of the most prominent and interesting line of the auroral spectrum, the line 5577, has hitherto remained unexplained. Vegard* has recently obtained a luminescent band from solid nitrogen, that he supposes, under very special conditions, may coincide with the auroral green line. ... spectra of pure helium and of pure oxygen were taken at different pressures and with various excitations, but no trace of 5577 or of any other new lines was obtained. ... Mixtures of helium, oxygen and nitrogen were excited, and it was found that the line 5577 could be photographed on the same plate with the nitrogen band system, thus reproducing in the laboratory practically the entire auroral spectrum. In ... mixtures of neon and oxygen ... neon enhanced the line 5577 in the same manner as helium. ... From Plate 20 it will be seen that all the lines except 5577 have been identified as strong lines in the spectrum of helium, hydrogen, oxygen, or mercury. ... It has been shown that this line must be attributed to some hitherto unknown spectrum of oxygen, and that it is not a limiting member of the ordinary band spectrum of oxygen. It has been observed faintly in highly purified oxygen when currents of high density have been used."[24]

Oxygen (O I) has two red lines at 630.0 and 636.4 nm. In the red there are the atomic oxygen transitions of the "forbidden oxygen red doublet at 6300.304 and 6363.776 Å (1D - 3P)"[25]. Atmospheric O2 has a red line at 686.72 nm.

"The oxygen abundance [may be determined] using the oxygen forbidden line at 630nm"[26]. "[R]atios [of] O/Fe ... are in agreement with the ratios found in the metal-poor red giants, suggesting that no real difference exists between dwarfs and giants."[26]

"The forbidden oxygen line (λ 630.03nm) is weak in dwarf stars"[26]

In the spectrum at right several red astronomy emission lines are detected and recorded at normalized intensities (to the oxygen III line) from the Ring Nebula. In the red are the two forbidden lines of oxygen ([O I], 630.0 and 636.4 nm), two forbidden lines of nitrogen ([N II], 654.8 nm and [N II], 658.4 nm), the hydrogen line (Hα, 656.3 nm) and a forbidden line of sulfur ([S II], 671.7 nm).

The spectrum above shows the lines in the visible due to emission from elemental oxygen.

Oxygen has several emission lines that occur in an electron cyclotron resonance (ECR) heated plasmas: 406.963, 406.99, 407.22, 407.59, 407.89, 408.51, 435.12, 441.489, and 441.697 nm from O II, and 434.045 nm from O VIII.[9]

"Electron temperatures are generally derived from the ratio of auroral to nebular lines in [O III] or [N II]."[27] "[B]ecause of the proximity of strong night-sky lines at λ4358 and λλ5770, 5791, the auroral lines of [O III] λ4363 and [N II] λ5755 are often contaminated."[27]

Liquid oxygen as shown on the right may not be perfectly clear.

"Liquid oxygen has a pale blue color and is strongly paramagnetic and can be suspended between the poles of a powerful horseshoe magnet. Liquid oxygen has a density of 1.141 kg/L and is cryogenic. freezing point: 50.5 K (-368.77 °F; -222.65 °C), boiling point: 90.19 K (-297.33 °F, -182.96 °C) at 101.325 kPa (760 mmHg)."[28]

Molecular oxygen (O2) [is] a colorless, odorless gas at room temperature.

Plasma cleaning involves the removal of impurities and contaminants from surfaces through the use of an energetic plasma created from gaseous species. Gases such as argon and oxygen, as well as mixtures such as air and hydrogen/nitrogen are used. The plasma is created by using high frequency voltages (typically kHz to >MHz) to ionise the low pressure gas (typically around 1/1000 atmospheric pressure), although atmospheric pressure plasmas are now also common.

"Oxygen-isotope analyses of ice and firn from the Saskatchewan Glacier, Canada, and the Malaspina Glacier, Alaska, show that variations in ratios are likely to be of considerable value in glaciological research."[29]

Fluorines[edit]

Main sources: Chemicals/Fluorines and Fluorines
This diagram contains the emission and absorption lines for the element fluorine. Credit: Alex Petty.
The center tube contains liquid fluorine. Credit: B. G. Mueller.

Fluorine has green emission lines that occur in plasmas at 526.83, 528.56, 529.76 and 530.27 nm from F VI.[9]

"Fluorine abundances for red giants of type K, Ba, M, MS, S, SC,N, and J [may be] obtained from the [infrared] rotation-vibration lines of the molecule HF. There appears to be a clear correlation between [F/O] and 12C/16O since N stars display F abundances up to 30 times the solar system value. This correlation points toward the He-burning shell as the site of F synthesis. The nuclear chain 14N(α,γ)18F(β+)18O(p,α)15N(α,γ)19F (where protons come from 13C(α,n)16O followed by 14N(n,p)14C) operating at the very beginning of He-burning is the most likely for 19F production in thermal pulses."[30]

The emission and absorption spectra of fluorine contains at least eight lines or bands from the cyan to the ultraviolet.[31]

Liquid fluorine in the tube on the right is yellow-orange in color.

"Variations in sea-surface temperature (SST) occur in association with changes in the Earth's climate. [...] However, despite a large effort, the glacial record of SST is still controversial, especially in the tropics. [Studies] of foraminifera demonstrated that the interspecific variability in Mg/Ca ratios of planktonic shells is strongly correlated with water temperature at the estimated calcification depth [...] Similar correlations were also observed Sr/Ca and F/Ca [...] possibly suggesting an important role for temperature on the elemental composition of foraminifera. [...] F/Ca of foraminafera is governed primarily by biological processes."[32]

Neons[edit]

Main sources: Chemicals/Neons and Neons
This is a visual spectrum of neon showing its many emission lines. Credit: McZusatz.
Spectrum = gas discharge tube: the noble gas: neon Ne, used with 1.8 kV, 18 mA, 35 kHz. ≈8" length. Credit: Alchemist-hp.

Neon has many lines across the red.

Like fluorine, neon has at least fourteen emission and absorption lines or bands from the cyan to the violet.[33]

"We analyze helium (He) and neon (Ne) isotope data sets from the southeast Pacific sector of the Southern Ocean collected in 1992 and 1994 and describe a new method to estimate glacial meltwater fluxes independent of previous approaches."[34]

Neon is a noble gas.

"21Ne exposure ages [are] of erosional glaciogenic rock surfaces on nunataks in northern Victoria Land, Antarctica: i) in the Prince Albert Mountains and ii) near Mesa Range. These nunataks are located directly at the margin of the polar plateau and therefore provide an immediate record of ice volume changes of the East Antarctic Ice Sheet, not biased by ice shelf grounding or narrow valley sections downstream the outlet glaciers. The sampling locations overlook the present ice surface by less than 200 m, but were last covered by ice 3.5 Ma BP (minimum age, not corrected for erosion). This strongly indicates that the ice sheet has not been substantially thicker than today since at least the early Pliocene, which supports the hypothesis of a stable East Antarctic Ice Sheet."[35]

Sodiums[edit]

Main sources: Chemicals/Sodiums and Sodiums
Sodium spectrum is ringrising 400 nm - 700 nm Credit: McZusatz.{{free media}}
Sodium metal is from the Dennis s.k collection. Credit: Dennis s.k.{{free media}}

"Glaciers in the Karakoram and western Himalaya (site 2 and 3) show high annual snow accumulation rates and high annual fluxes of calcium, sodium, chloride, sulfate, and nitrate."[36]

Magnesiums[edit]

This image shows the optical emission lines of magnesium. Credit: teravolt.
Crystalized magnesium is shown. Credit: Mark Fergus, CSIRO.{{free media}}
This image is a visual close up of green sand which is actually olivine crystals that have been eroded from lava rocks. Credit: Brocken Inaglory.
This is a visual image of a forsterite crystal. Credit: Azuncha.
This is a small volcanic bomb of (black) basanite with (green) dunite. Credit: B.navez.

At right is a visual close up of green sand which is actually olivine crystals that have been eroded from lava rocks. Some olivine crystals are still inside the lava rock.

Forsterite (Mg2SiO4) is the magnesium rich end-member of the olivine solid solution series.

Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe.[37] In 2011 it was observed as tiny crystals in the dusty clouds of gas around a forming star.[38]

Two polymorphs of forsterite are known: wadsleyite (also orthorhombic) and ringwoodite (isometric). Both are mainly known from meteorites.

At lower right is an image of a small volcanic bomb of (black) basanite with (green) dunite.

Dunite is an igneous, plutonic rock, of ultramafic composition, with coarse-grained or phaneritic texture. The mineral assemblage is greater than 90% olivine, with minor amounts of other minerals such as pyroxene, chromite and pyrope. Dunite is the olivine-rich end-member of the peridotite group of mantle-derived rocks. Dunite and other peridotite rocks are considered the major constituents of the Earth's mantle above a depth of about 400 kilometers. Dunite is rarely found within continental rocks, but where it is found, it typically occurs at the base of ophiolite sequences where slabs of mantle rock from a subduction zone have been thrust onto continental crust by obduction during continental or island arc collisions (orogeny). It is also found in alpine peridotite massifs that represent slivers of sub-continental mantle exposed during collisional orogeny. Dunite typically undergoes retrograde metamorphism in near-surface environments and is altered to serpentinite and soapstone.

Magnesium (Mg I) has an absorption band at 416.727±2.9 nm with an excitation potential of 4.33 eV.[39]

Magnesium (Mg II) has an absorption band at 439.059±6.6 nm with an excitation potential of 9.96 eV.[39]

"Glaciers in the Karakoram and western Himalaya (site 2 and 3) show high annual snow accumulation rates and high annual fluxes of calcium, sodium, chloride, sulfate, and nitrate."[36]

Aluminums[edit]

Main sources: Chemicals/Aluminums and Aluminums
Aluminium spectrum is for 400 nm - 700 nm Credit: McZusatz.{{free media}}
Sampling locations are in and along the upper 12 km of the Rio Quilcay, Cordillera Blanca, Peru. Main stream samples are labeled 1–24, tributaries A–F. Credit: Sarah K. Fortner, Bryan G. Mark, Jeffrey M. McKenzie, Jeffrey Bury, Annette Trierweiler, Michel Baraer, Patrick J. Burns, and LeeAnn Munk.
Tributary C feeds the Northeast Branch of the Rio Quilcay, Peru. This tributary has abundant ochreous precipitates. Credit: Sarah K. Fortner, Bryan G. Mark, Jeffrey M. McKenzie, Jeffrey Bury, Annette Trierweiler, Michel Baraer, Patrick J. Burns, and LeeAnn Munk.
Chunk of aluminium is 2.6 grams, 1 x 2 cm, cut from a melted ingot. Credit: Unknown.{{free media}}

"The aluminium abundance was derived from the resonance line at 394.4nm, and Al is underabundant by ∼ −0.7 dex with respect to iron."[40] "These abundances are the LTE values; no NLTE corrections, as prescribed by Baumüller and Gehren (1997) and Baumüller et al. (1998), have been applied. The prescribed NLTE corrections for Teff = 6500K, log g = 4.0, [Fe/H] = –3.0 are –0.11 ... for ... Al .... If we assume these values to apply for our lower-gravity star [CS 29497-030], then Al follows iron"[40]. The elemental abundance ratios for CS 29497-030 of aluminum are [Al/H] = -3.37, [Al/Fe] = -0.67.[40]

Both Al I absorption lines at 394.401±8.5 and 396.152±6.5 have been measured for Sirius.[39]

"As Andean glaciers recede, there has been an increase in seasonal discharge and in catchments with the least glacierized area and a decrease in total annual discharge [...] Dry season examinations, including this study, are particularly important because during this period glacial melt provides up to 40% of the total discharge in the Cordillera Blanca (Mark et al., 2005). The dry season thus provides the greatest potential opportunity to evaluate water quality deterioration related to glacial retreat. [...] In the Cordillera Blanca, the exposure of fresh sulfide-rich lithologies by retreating glaciers (Wilson et al., 1967) is thus integral to the biogeochemistry of proglacial streams. [...] the dry season geochemistry of trace and minor elements was examined in the proglacial Rio Quilcay from within 1 km of its glacier origins to 12 km downstream."[41]

The "Rio Quilcay [is] a glacial-fed tributary to the Upper Rio Santa in the uppermost 12 km at elevations ranging from approximately 4800 to ~3800 m.a.s.l. [...] The sampled region of the Rio Quilcay receives glacial melt directly and indirectly from two proglacial lakes: Cuchillacocha and Tulpacocha. Geology in this region of the Cordillera Blanca includes pyrite schists and phyllite and pyrite-bearing quartzite intruded by a central granodiorite-tonalite batholith all overlain by clastic sediments deposited during glacial retreat (Wilson et al., 1967). Sulfide-rich lithologies are prevalent especially in the north-eastern high-altitude regions of the Cordillera Blanca (e.g. the Rio Quilcay Valley) with fresh exposures resulting from glacial scour (Wilson et al., 1967). Many headwaters in the Cordillera Blanca, including the Rio Quilcay and its tributaries, have ochreous precipitates"[41]

"Aluminum, Ca, Fe, K, Mn, Na, and Si were determined using an Optima 3000 DV Inductively Coupled Plasma-Optical Emission Spectrometer (ICP-OES) using five calibration standards that bracketed the range of concentrations within the samples, excepting the three highest samples which were diluted 1:10 before analyses. Cobalt, Cu, Ni, Pb and Zn were determined on a Perkin–Elmer Sciex Elan 6000 Inductively Coupled Plasma-Mass Spectromenter (ICP-MS) also using five calibration standards, however with no sample dilution. All element results were drift corrected. Sulfate and NO3- were determined using a Dionex DX-120 ion chromatograph (IC). Only SO42- is reported because other anions fall near detections limits (DLs) in the higher elevation samples, or represent less than 5% of the charge balance in the pH < 4 streams."[41]

It "is likely that both the sulfide-rich lithology underlying the Rio Quilcay and the near-glacier sample locations enhanced sulfide weathering, and generated exceptionally high cation loads."[41]

"Elevated dissolved Al, Fe and Cu concentrations (6.1mg/L, 21.4 mg/L, 6.1 lg/L) were observed at site 11, 0.3 km immediately downstream of a moraine. Concentrations of these elements increased by more than four times the concentrations at site 10. Concentration gains were likely associated with glacier melt rapidly weathering minerals within the moraine (Brown, 2002)."[41]

"Tributary C also influenced the chemical composition of the stream immediately below its inflow at site 13. In fact, Fe reached the second highest concentration reported (12.8 mg/L) and dissolved Al, Mn, Co, Cu, Ni and Zn concentrations also increased above their upstream values. Tributary C overlays a region with enhanced sulfide mineral oxidation [image at the right]. Evidence for this includes a major cation: SO42- equivalent ratio of 1, and abundant algal mats covered with yellow and orange precipitates (Bigham et al., 1996). In addition, dissolved Al and Zn increased an additional 270% and 160% relative to site 13–14, respectively, and after the inflow of tributary D."[41]

Silicons[edit]

Main sources: Chemicals/Silicons and Silicons
Close up photo is of a piece of purified silicon. Credit: Enricoros.{{free media}}
Silicon spectrum is from 400 nm - 700 nm. Credit: McZusatz.{{free media}}

Silicon (Si II) has two absorption bands at 412.805±10.8 nm and 413.088±13.0 nm with excitation potentials of 9.79 eV and 9.80 eV, respectively.[39]

Silicon has an absorption line (Si IV) at 408.9 nm.[42]

"The relatively long-lived radionuclide of silicon, 32Si, finds important applications as a tracer for studying aqueous geochemistry, biogeochemical cycles of silicon in the oceans, and the chronology of glaciers and biogenic silica-rich sediments in lacustrine and marine environments."[43]

Phosphoruses[edit]

White phosphorus and resulting allotropes, including violet phosphorus, are indicated. Credit: UserXresu.
Phosphorus spectrum is for emission lines between 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Waxy white (yellow cut), red (granules centre left, chunk centre right), and violet phosphorus are shown. Credit: white phosphorus, BXXXD, red phosphorus Tomihahndorf, and violet phosphorus Maksim.{{free media}}

Elemental phosphorus can exist in several allotropes; the most common of which are white and red solids. Solid violet and black allotropes are also known.

It would appear that violet phosphorus is a polymer of high relative molecular mass, which on heating breaks down into P2 molecules. On cooling, these would normally dimerize to give P4 molecules (i.e. white phosphorus) but, in vacuo, they link up again to form the polymeric violet allotrope.

"Phosphorus has been shown to be deficient in glacial environments, and thus is one of the limits on microbial growth and activity."[44]

"The P species in the titania lattice should be the dominant group responsive to visible light, whereas the P species on the surface could retard the phase transition of anatase to rutile and increase the surface area and adsorption capability."[45]

"The P species in the titania lattice should be the dominant group responsive to the visible light activity, although P species on the surface could retard the phase transition of anatase to rutile, and increase the surface area and adsorption capability, consequently enhancing the photocatalytic activity."[45]

Sulfurs[edit]

Main sources: Chemicals/Sulfurs and Sulfurs
Sulfur emission spectrum is from 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This is a sample of sulfur. Credit: Ben Mills.{{free media}}

"Both sulfur and oxygen isotopes of sulfate preserved in ice cores from Greenland and Antarctica have provided information on the relative sources of sulfate in the ice and their chemical transformation pathways in the atmosphere over various time periods."[46]

Chlorines[edit]

Main sources: Chemicals/Chlorines and Chlorines
Chlorine emission spectrum is from 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Liquid chlorine is contained in a flask for analysis. Credit: Workingclass91.
Liquid chlorine is under pressure in an "acrylic glass" (i.e., Plexiglas, Lucite) cube. Credit: Alchemist-hp.
Chlorine gas is contained in an ampoule. Credit: W. Oelen.

"Chlorine-36 is produced in rocks at the surface of the earth by cosmic-ray spallation, mainly of K and Ca, and by activation of 35Cl by cosmic-ray neutrons (PHILLIPS et al., 1986; FABRYKA-MARTIN, 1988). Cosmogenic 36Cl significantly above subsurface concentrations is produced only to depths of a few meters below the earth’s surface (FABRYKA-MARTIN, 1988; LAL, 1987), and its buildup has been shown to be a regular function of time (PHILLIPS et al., 1986). Zreda et al. (1990, 1991) have determined 36Cl production rates (normalized to sea level and 90” N latitude) of 4,160 ± 310 atoms 36Cl (mol K)-1 yr-1 and 3,050 ± 210 atoms 36Cl (mol Ca)-1 yr-1, and a thermal neutron capture rate of (3.07 ± 0.24)*105 neutrons (kg rock)-1 yr-1. Meteor Crater is an excellent subject for cosmogenic nuclide accumulation dating because we can identify and sample one geological unit (the Kaibab Formation) that was virtually completely shielded from cosmic rays by 10 m of Moenkopi Sandstone prior to the impact (RODDY, 1978). Boulders of Kaibab Formation were nearly instantaneously exposed to cosmic radiation when they were ejected from the crater by the impact. The date of the impact can be determined by measuring the amount of cosmogenic 36Cl that has accumulated, provided that the boulder surfaces are not strongly eroded. Erosion rates in the range of millimeters per thousand years will have little effect on cosmogenic 36Cl dates, but loss of slabs of decimeter or greater thickness would reduce the apparent age."[47]

36Cl "is created by high-energy cosmic-ray neutron reactions on potassium and calcium and low energy neutron reactions on stable chlorine."[48]

"Chlorine-36 buildup dating has successfully been applied to glacial moraines in the eastern Sierra Nevada (California) and to lava flows and meteorite impact craters in the western United States."[48]

On the right is liquid chlorine (Cl2) contained in a flask for analysis. Liquid chlorine is yellow in color.

Image on the left is an ampoule containing liquid chlorine. It has been liquefied under pressure at >7.4 bar, sealed in the quartz vial (ampoule), further sealed in an "acrylic glass" (i.e., Plexiglas, Lucite) cube, cube edge length: 5 cm.

Chlorine is a toxic, green gaseous chemical element.

Argons[edit]

Main sources: Chemicals/Argons and Argons
Argon emission spectrum has enhanced lines. Credit: Abilanin.{{free media}}
Liquid argon drips off of a small block of solid argon. Credit: Fir0002.
Spectrum = gas discharge tube: the noble gas: argon Ar, used with 1.8 kV, 18 mA, 35 kHz. ≈8" length.Alchemist-hp.

Argon has three emission lines that occur in an electron cyclotron resonance (ECR) heated plasmas: 497.216, 500.9334, and 506.204 nm from Ar II.[9]

Argon has an emission line occurring in the solar corona at 553.6 nm from Ar X.[49]

Argon has an emission line that occurs in an electron cyclotron resonance (ECR) heated plasmas: 473.591 nm from Ar II.[9]

Argon has several emission lines that occur in an electron cyclotron resonance (ECR) heated plasmas: 426.653, 428.29, 433.12, 434.8064, 437.075, 437.967, 442.60, and 443.019 nm from Ar II.[9]

While argon is a gas at room temperature and pressure, it becomes a solid at liquid nitrogen temperature and melts to a liquid as in the image on the right when removed from the liquid nitrogen.

Argon is a noble gas.

"Nitrogen and argon isotopes in trapped air in Greenland ice show that the Greenland Summit warmed 9 ± 3°C over a period of several decades, beginning 14,672 years ago."[50]

Potassiums[edit]

This is a potassium emission-line spectrum over the range 400 nm - 700 nm. Credit: McZusatz.
Cut potassium (kalium) pieces show metallic silver color. Credit: Dennis s.k.{{free media}}

"The group [of potassium lines] at λλ 535, 510, and 495 Å "showed no trace of structure even in an arc of but half an ampere."[51]

"Potassium and calcium concentrations are high relative to other cations in glacial water, probably due to dissolution of soluble trace phases, such as carbonates, exposed by comminution, and cation leaching from biotite."[52]

Calciums[edit]

Main sources: Chemicals/Calciums and Calciums
This is a calcium emission spectrum covering the range: 400 nm - 700 nm. Credit: McZusatz.
Pure calcium is in a protective argon atmosphere. Credit: Matthias Zepper.{{free media}}

Calcium (Ca) has green emission lines at 526.170 nm and 526.556 nm as observed in solar limb faculae.[53]

As of 1977, "model calculations cannot reproduce the observed breadth of the Ca II λ3933 line in Da,F stars like Ross 627 without appealing to an unknown line-broadening mechanism".[54]

Calcium has a line occurring in the solar corona at 408.63 nm of Ca XIII.[49]

Calcium (Ca I) has two absorption bands, 422.673±4.5 nm and 430.253±0.6.[39] The second has an excitation potential of 1.89 eV.[39]

Calcium (Ca II) has an absorption band, 393.366±55.0.[39]

"Heinrich Layers are found in the North Atlantic Ocean as well-constrained markers of catastrophic iceberg surges from the Pan-Atlantic ice sheets during the last glacial cycle. Their physical and geochemical characteristics [...] are predominantly due to the source sediments of the ice-rafted debris (IRD) on the one hand (magnetic susceptibility, color, carbonate content) and the response of the palaeo-environment on the other hand (carbonate content, foraminiferal assemblage)."[55]

"Sediment cores in the Porcupine Seabight (West off Ireland) have shown the presence of Heinrich Events without the diagnostic changes in magnetic susceptibility (MS) [...] the concentration of ice-rafted debris (commonly referred to as the fraction > 150 μm) increases towards the culmination of HL2, marked by an increase in MS, [X-ray fluorescence] XRF Ca and the percentage of N. pachyderma s."[55]

The "zone where the density increases is marked by a cloud of fine and highly dense particles surrounding the IRD. [The] fine clayey “background” matrix throughout the core [consists] of zoned dolomites. [...] the mineralogical analyses [suggest] a predominant volcanic source for the magnetic susceptibility. [Both] XRF Fe and Ti show significant decreases near the HL culmination".[55]

Scandiums[edit]

Main sources: Chemicals/Scandiums and Scandiums
Scandium emission spectrum is from 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Scandium is the first transition metal and the first rare earth element. Credit: Hi-Res Images of Chemical Elements.{{free media}}

Scandium is the first transition metal and the first rare earth element, the latter also includes yttrium and the lanthanoids. The ignoble light metal has only a few applications, because its chemistry isn't so complex and it also is rather expensive. It is used in high-quality, light alloys, e.g., for frames of racing bicycles.

Scandium (Sc II) has an absorption band, 424.683±1.0 nm, with an excitation potential of 0.31 eV.[39]

"Neutron activation analysis was used to deterimne the total [lanthanum] La and [scandium] Sc content of three soils developed from loess-capped glacial till. The profiles were classified as Gray-Brown Podzolics (Hapludalfs) overlying paleosols developed in Rockain till. The total La content in the less than 250µ fraction of these soils ranged from 18.1 to 37.1 ppm, with an average content of 23.7 ppm in the loess and 28.5 ppm in the glacial till. Total Sc in the soils ranged from 5.1 to 10.9 ppm with average contents of 6.5 and 9.0 ppm in the loess and glacial till, respectively. Translocation by pedogenic processes was indicated by the accumulation of these elements in the argillic B horizons. Correlation coefficients of La and Sc with clay percentages in the profiles were 0.79 and 0.88, respectively."[56]

Titaniums[edit]

Main sources: Chemicals/Titaniums and Titaniums
This is an emission spectrum that covers the visible range: 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Titanium strips inside a glass jar are part of the Everest Element Set from Russia. Credit: RTC.{{free media}}

Titanium (Ti) has green emission lines at 521.97, 522.268, 522.413, 524.729, and 526.596 nm as observed in solar limb faculae.[53]

Titanium (Ti II) has an absorption band, 391.346-441.108 nm, with an excitation potential range of 0.60-3.08 eV.[39]

Titanium has two emission lines at 456.3757 and 457.1971 nm from Ti II.[57]

"Till collected from surface exposures within the valley of the Hudson River south of the Sanford Hill magnetite-ilmenite ore deposit in the Adirondack Mountains of New York is composed primarily of plagioclase, pyroxene, garnet, magnetite, and ilmenite [FeTiO3]. The concentration of magnetite and ilmenite in bulk till both decrease exponentially with increasing distance south of the ore bodies because of dilution by the entrainment of plagioclase and garnet + pyroxene from the bedrock and from older till deposits in the valley. Evidence for comminution of magnetite and ilmenite is provided by decreasing abundances of these minerals in the coarse fractions (1000-125 µm) and corresponding increases in the fine fraction (<125 µm). The apparent rate of comminution of ilmenite as a function of transport distance is significantly greater than that of magnetite, which causes ilmenite to be concentrated in the fine fraction of till compared to magnetite."[58]

Vanadiums[edit]

Main sources: Chemicals/Vanadiums and Vanadiums
This is an emission spectrum that covers the visible range: 400 nm - 700 nm. Credit: McZusatz.
Vanadium pieces are shown. Credit: W. Oelen.{{free media}}
Oxidation states of vanadium are shown from left +2 (lilac), +3 (green), +4 (blue) and +5 (yellow). Credit: Steffen Kristensen.

The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2-5. In aqueous solution the colours are lilac V2+(aq), green V3+(aq), blue VO2+(aq) and, at high pH, yellow VO42-.

Vanadium (V II) has an absorption band, 392.973-403.678 nm, with an excitation potential range of 1.07-1.81 eV.[39]

"The average contents of vanadium in the glacial and alluvial deposits of the Altai are comparable with those of Transbaikalia."[59]

"In Transbaikalia, elevated vanadium contents are characteristic of granitic gneisses (324 ppm), syenites (204 ppm), and granitoids (162 ppm), whereas basalts are poor in vanadium (83 ppm) [2]."[59]

"The lowest values are characteristic of glacial sandy loams and alluvial deposits."[59]

Chromiums[edit]

Main sources: Chemicals/Chromiums and Chromiums
This is a visible emission-line spectrum for chromium over the range: 400-700 nm. Credit: McZusatz.
A hunk of chromium metal is shown. Credit: W. Oelen.{{free media}}

A chromium emission line occurs in plasmas at 520.84 nm from Cr II.[9]

Chromium (Cr) has green emission lines at 522.091, 522.407, 524.336, 524.757, and 526.572 nm as observed in solar limb faculae.[53]

Cr+ has an emission line at 524.677 nm as observed in solar limb faculae.[53]

Chromium has two emission lines at 455.8650 and 458.8199 nm from Cr II.[57]

Chromium (Cr) has emission lines that occur in plasmas at 425.435, 427.48, and 428.972 nm from Cr I.[9]

Chromium has absorption lines that occur at 425.435-428.972 nm from Cr I and 400.333-428.421 nm, 3.09-6.46 eV from Cr II near Sirius.[39]

For "the Pinchi Mine area [...] mercury ore was transported over a distance of 12 km, as measured in the clay-sized fraction (< 0.002 mm) of till, and could have been transported over 24 km according to heavy mineral concentrates (specific gravity >3.3) of this same sediment. Antimony, chromium, and nickel dispersal trains were also detected in the region."[60]

Manganeses[edit]

Manganese emission spectrum is from 400 nm - 700 nm Credit: McZusatz.{{free media}}
Two pieces of manganese metal are shown. Credit: W. Oelen.{{free media}}

Manganese (Mn I) has two absorption bands at 403.449±1.4 nm and 405.554±0.8 nm, where the second has an excitation potential of 2.13 eV.[39]

Manganese (Mn II) has an absorption band at 420.638±0.8 nm with an excitation potential of 5.37 eV.[39]

"In glacial marine sediments from the St. Lawrence estuary, iron varies between 1.32 and 5.42%, manganese between 0.043 and 0.28%, and titanium between 0.31 and 0.64%."[61]

"Analyses of individual sediment size-fractions show that Fe, Mn, and Ti concentrations generally increase with decreasing grain size."[61]

Irons[edit]

Main sources: Chemicals/Irons and Irons
This digitally altered image shows the Fraunhofer lines. Credit: Saperaud.
Iron is a silvery, relatively reactive metal, which is very abundant and is used for multiple purposes. Credit: Hi-Res Images of Chemical Elements.{{free media}}

Fraunhofer's original (1817) designations of absorption lines in the solar spectrum include the E line for neutral iron at 526.96 nm.

Iron (Fe) has green emission lines at 522.319, 522.553, 524.705, 524.911, 525.021, 525.065, 526.262, 526.288, 526.331, 526.368, 526.656, and 526.727 nm as observed in solar limb faculae.[53]

"[G]round-based observations (around the solar limb) [are] of the 530.3 nm coronal line. This green solar corona is emitted by Fe XIV ions ... Green coronal intensities (Fe XIV, 530.3 nm) obtained from different coronal stations vary greatly among themselves."[62]

Fe+ has a green emission line at 526.480 nm as observed in solar limb faculae.[53]

Iron has two emission lines occurring in the solar corona at 637.451 nm from Fe X and 705.962 nm from Fe XV.[49]

Iron has a line occurring in the solar corona in the violet at 398.69 nm of Fe XI.[49]

Iron (Fe I) has an absorption band at 392.291-440.475 nm with an excitation potential range of 0.05-2.46 eV.[39]

Iron (Fe II) has an absorption band at 393.829-438.538 nm with an excitation potential range of 1.66-2.77 eV.[39]

Iron (Fe II) has an emission line at 489.1 nm.[63]

The Fraunhofer G line at 430.790 nm is from iron.

"Dissolved iron (DFe) and total dissolvable Fe (TDFe) were measured in January–February 2009 in Pine Island Bay, as well as in the Pine Island and Amundsen polynyas (Amundsen Sea, Southern Ocean). Iron (Fe) has been shown to be a limiting nutrient for phytoplankton growth, even in the productive continental shelves surrounding the Antarctic continent."[64]

"At the southern end of Pine Island Bay, the [Circumpolar Deep Water] CDW upwelled under the Pine Island Glacier, bringing nutrients (including Fe) to the surface and melting the base of the glacier."[64]

"The largest source was Fe input from the PIG, which could satisfy the total Fe demand by the phytoplankton bloom by lateral advection of Fe over a range of 150 km from the glacier."[64]

"Total-Fe (TFe) and total-P (TP) concentrations are high in all three glacial streams, but the ratios of soluble reactive phosphate (SRP) to TP are very different. The Upper Manso Stream that drains the Manso Glacier has relatively low SRP (0.01-0.23 PM), representing a small fraction of its TP (O. l-5%). The SRP of the two streams draining smaller side glaciers (0.12-0.69 PM) represents a much larger portion of their TP (20-32%)."[65]

"TFe, dissolved sulfate, and δ 34S data suggest that pyrite oxidation is the most likely weathering reaction contributing sulfate to the Upper Manso Stream but not to the two smaller glacial-fed streams, in which atmospheric inputs can account for all of the sulfate."[65]

Pure iron as in the image on the right is a silvery, relatively reactive, soft metal, which is very abundant and is used for multiple purposes. Commonly it is alloyed together with carbon and other elements, to become steel. The number of different steels is very high, their characters vary over a wide span. Sometimes pure iron occurs in nature, but most is found in ores. Meteorites, that hit Earth's ground and don't evaporate before, often are iron meteorites. Iron can be seen as an energetic ideal state of matter. Smaller atoms can set energy free by fusion, larger atoms by fission, but from iron no nuclear energy can be won. Iron 56 and 58 and nickel 62 have the highest binding energy per nuclear particle. Very big stars form an iron core shortly before their final collapse and the following supernova. Iron is essential for mammals and makes our blood red. Iron is known to humanity for several millennia and has shaped our culture and civilization like no other element.

Cobalts[edit]

Main sources: Chemicals/Cobalts and Cobalts
Cobalt emission spectrum is from 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This piece of pure cobalt has a mass of 3 grams. Credit: Unknown.{{free media}}
The distribution of the concentrations of dissolved cobalt (Cod) observed in May 1994 (filled circles) and July-August 1995 (shaded squares) are presented. Credit: Charles-Philippe Lienemann, Martial Taillepert, Didier Perret, and Jean-François Gaillard.

"On glacier surfaces conditions [...] exist for aerosols and airborne dust deposited with anthropogenic and natural radionuclides attached on their surfaces. In the course of agglomeration processes initiated by melting and redistribution, these particles may concentrate in small depressions, ice pockets, ablation edges etc. and form substances called cryoconites ('ice dust'). As there is no other matrix than the original aerosol particles, cryoconites are a sink for radionuclides and airborne pollutants and their activity levels are among the highest produced by natural processes observed in environmental media. 137Cs activities found on glaciers in the Austrian alps are between 255 and 136.000 Bq/kg and predominantly derived from Chernobyl, but also from global fallout. Further anthropogenic radionuclides detected are 134Cs, 90Sr, 238,239+240Pu, 241Am, 125Sb, 154Eu, 60Co and 207Bi [in] combination with the naturally occurring radionuclides 7Be and 210Pb and isotopic ratios such as 134Cs/137Cs".[66]

The "concentration of dissolved Mn and Co [figure at the right] increase sharply across the oxic/anoxic transition, from 5 to 5.5 m depth. The concentration of Co rises from detection limit, when O2 is still present, to 6.8 nM and 12 nM, respectively, for May 1994 and July-August 1995."[67]

In the oxic mixolimnion, dissolved Co remains primarily under its free hydrated form (Co[H2]2+6, whereas in the anoxic bottom waters it seems to be primarily present as a sulfide complex (CoS0).

Nickels[edit]

Main sources: Chemicals/Nickels and Nickels
This is an emission-line spectrum for nickel over the visible range: 400-700 nm. Credit: McZusatz.{{free media}}
This piece of Ni is about 3 cm in size. Credit: Materialscientist.{{free media}}

Nickel has an emission line occurring in the solar corona at 511.603 nm from Ni XIII.[49]

Nickel has an emission line occurring in the solar corona at 670.183 nm from Ni XV.[49]

Nickel has three emission lines occurring in the solar corona at 380.08 nm of Ni XIII and 423.14 nm and 431.1 of Ni XII.[49]

Nickel has an absorption band at 401.550-436.210 nm with an excitation potential of 4.01 eV.[39]

In "the Arctic Archipelago and in parts of northern Baffin Island and Boothia Peninsula the glaciers were apparently cold-based and effected little erosion of the preglacial landscape."[68]

Nickel "occurs in concentrations far above the crustal average in basic and ultrabasic igneous rocks. Where a glacier has eroded nickel-enriched zones in basalts, gabbros, serpentinized periodotites, and similar basic or ultrabasic igneous rocks, or their metamorphic equivalents, nickel-enriched glacial debris may be spread out in the form of a glacial dispersal train."[68]

"Nickel occurs in unweathered glacial sediments in the same mineral phases as those in which it is found in rocks."[68]

"Where a glacier has overridden ultrabasic rocks, nickel may still be present in sulfide grains, but its presence in silicates such as olivine, serpentine, amphiboles, biotite, and talc, can lead to very high bulk nickel compositions in till or derived sediments."[68]

Coppers[edit]

Main sources: Chemicals/Coppers and Coppers
Copper emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This is a Landsat Thematic Mapper image with overlain geological structures. Credit: I.M. Kettles, A.N. Rencz, and S.D. Bauke.
A large, sculptural specimen of penny-bright copper is from Arizona. Credit: Robert Lavinsky.

"Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion."[69]

"A group of pixel areas north of Lake Superior [in the Landsat image on the right] take the form of a linear band which lies along the northern edge of the Port Coldwell Complex (D). [...] there are numerous Cu showings along the northern edge of the Port Coldwell complex (Ontario Division of Mines, 1971)."[70]

Zincs[edit]

Main sources: Chemicals/Zincs and Zincs
Zinc emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Pure zinc metal wedge is shown. Credit: United States Geological Survey.{{free media}}

"Satellite images taken over the past several decades show the dramatic disappearance of ice, including on the island’s inland areas, where the ice fields can in places be up to three and a half kilometers deep."[71]

"Along with uranium, zinc, iron ore, copper and gold, Greenland’s ancient rocks also harbor large quantities of those minerals known as “rare earth,” among them lanthanum, cerium, neodymium, praesodymium, terbium and yttrium."[71]

Galliums[edit]

Main sources: Chemicals/Galliums and Galliums
Gallium emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This is a liquid drop of gallium. Credit: RTC.
This solid gallium is fresh and after some time (2 months) at room temperature. Credit: Hi-Res Images of Chemical Elements.{{free media}}

The image on the right is a drop of liquid gallium.

Gallium "enrichments are observed in the deep waters of the Norwegian Sea and Iceland Basin."[72]

"If northern deep water formation occurs at lower latitudes during glacial periods, the amount of sediment resuspension in the formation areas is likely to be affected with concomitant effects on the trace element content of newly formed northern-source deep waters."[72]

"At higher growth temperatures(>600'C) the lifetimes of the alkyl-gallium species are much shorter and the growth front dynamics should begin to look more like MBE since atomic gallium will be the dominant group III surface species."[73]

Germaniums[edit]

Germanium emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This chunk is 12 grams of polycrystalline germanium, 2 x 3 cm. Credit: Jurii.{{free media}}

"Data from three glacial meltwater streams draining Mt. Tronador in the southern Argentine Andes (72°W, 41°S) show that subglacial pyrite oxidation and the subsequent precipitation of iron oxides strongly influence dissolved phosphate concentrations but do not appear to affect dissolved germanium concentrations."[65]

"Dissolved Ge appears to show no preferential sorption relative to dissolved silica, in contrast to the speculation that Ge preferentially sorbs on fresh iron hydroxyoxide surfaces."[65]

"Since the energy of the 3.11 MeV peak observed here coincides with that of the dominant group in the delayed proton spectrum of Ca, it has been necessary to evaluate the possibility that Ca, produced in reactions on the small oxygen contamination in the target, could be the source of this activity"[74] This is with respect to beta-delayed proton decay of 61Ge.[74]

Arsenics[edit]

Main sources: Chemicals/Arsenics and Arsenics
Arsenic emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Ultrapure metallic arsenic is kept under argon, 1-2 grams. Credit: Hi-Res Images of Chemical Elements.{{free media}}
Native arsenic such as this specimen is found in silver ore veins. Credit: Amethyst Galleries, Inc.

Native arsenic such as in the image on the left occurs in silver ore veins.

"The dominant group V source is arsenic, although antimony and phosphorous sources are not atypical."[75]

Seleniums[edit]

Main sources: Chemicals/Seleniums and Seleniums
Selenium emission spectrum for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
These are native selenium needles from Katharine mine, Radvanice, Czech Republic. Credit: Asahi.
Selenium (native) with pen for scale is from the mineral collection of Brigham Young University Department of Geology, Provo, Utah. Credit: Andrew Silver, USGS.
The dark gray mineral in the yellow sandstone is native selenium. Credit: James St. John.

On the left is a photograph of native selenium from the mineral collection of Brigham Young University Department of Geology, Provo, Utah.

The second image down on the left shows dark gray selenium in sandstone from Westwater Canyon Section 23 Mine Grants, New Mexico.

In the magnified image of the sample on the right are native selenium needles.

Bromines[edit]

Main sources: Chemicals/Bromines and Bromines
Bromine emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Liquid bromine is contained in a safety jar. Credit: W. Oelen.

Bromine is a halogen that is a liquid at room temperature and pressure.

"Br and Pb were more evenly distributed over the various food groups; the group 'nuts' showed the highest content of Br (about 8 mg/kg), but for Pb such a dominant group could not be indicated."[76]

Kryptons[edit]

Main sources: Chemicals/Kryptons and Kryptons
Krypton emission spectrum for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Spectrum = gas discharge tube: the noble gas: krypton Kr. Used with 1,8kV, 18mA, 35kHz. ≈8" length. Credit: Alchemist-hp.
Vial contains glowing ultrapure krypton. Credit: Jurii.{{free media}}

Krypton is a noble gas.

Krypton has 5 stable isotopes (80, 82, 83, 84, 86).

Rubidiums[edit]

Main sources: Chemicals/Rubidiums and Rubidiums
Rubidium emission spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
Rubidium metal sample is enclosed in a quartz ampule to prevent oxidation. Credit: Dnn87.{{free media}}
This image shows the flame test for Rubidium. Credit: Didaktische.Medien.

Rubidium occurs in the mineral lepidolite and is found through the use of a spectroscope because of the bright red lines in its emission spectrum.

On Earth, natural rubidium occurs as two isotopes: 72% is the stable isotope, 85Rb; 28% is the slightly radioactive 87Rb, with a half-life of 49 billion years.

Strontiums[edit]

This is a magnesium-strontium phase diagram. Credit: A.A. Nayeb-Hashemi and J.B. Clark.

Strontium at room temperature crystallizes in a fcc structure (α-Sr).

According to the phase diagram on the left, α-Sr transforms to γ-Sr (bcc) at 547°C.

Native strontium does not appear to occur on the surface of the Earth.

Strontium (Sr II) has two absorption bands: 407.771±11.3 nm and 421.552±10.4 nm.[39]

Yttriums[edit]

Main sources: Chemicals/Yttriums and Yttriums

Yttrium (Y II) has an absorption band from 395.035 to 439.802 nm, with an excitation potential range of 0.10-0.13 eV.[39]

The orange system [in orange astronomy] is a number of emission lines very close together forming a band in the orange portion of the visible spectrum. These lines are usually associated with particular molecular species, including ScO, YO, and TiO.[77]

Zirconiums[edit]

This is a binary phase diagram of the iron-zirconum system. Credit: D. Arias and J.P. Abriata.

As the Fe-Zr phase diagram on the left demonstrates, zirconium has a hcp structure (α-Zr) at lower temperatures, including room temperature, and a bcc structure (β-Zr) at higher temperatures up to melting.

"Zirconium isotopic abundances [may be] determined from ZrO bandheads near 6925 Å via synthetic spectra for a sample of S stars."[78]

Zirconium (Zr II) has an absorption band, 395.824-415.624 nm, with an excitation potential of 0.52-0.75 eV.[39]

Niobiums[edit]

Main sources: Chemicals/Niobiums and Niobiums
This is an iron-niobium phase diagram. Credit: E. Paul and L.J. Swartendruber.

As can be seen in the iron-niobium phase diagram on the left, niobium is single phase (α-Nb) up to its melting temperature. This is a bcc structure.

It appears to be the case that native niobium does not occur in the surface rocks on Earth.

Molybdenums[edit]

This is a scanning electron micrograph of native molybdenum particles in lunar regolith. Credit: A. V. Mokhov and P. M. Kartashov.
This is a calculated iron-molybdenum phase diagram. Credit: Computational Thermodynamics Inc.

The electron micrograph on the right shows a couple of pieces of native molybdenum found in lunar regolith at the Luna 24 landing site after transport back to Earth and analysis.

The phase diagram for the iron-molybdenum system demonstrates that molybdenum is bcc (α-Mo) for its intermediate and higher temperatures. It's also bcc at room temperature.

Technetiums[edit]

and

These "reactions probe precisely the time scale and neutrino-flux component of most interest: the boron-8 neutrino luminosity, which is the most sensitive monitor of variations in the solar core temperature, during and before the Pleistocene epoch. (The half-lives of technetium-97 and -98 are, respectively, 2.6 and 4.2 million years; the reaction on molybdenum-98 is induced only by the high-energy boron-8 neutrinos; and the reaction on molybdenum-97 may sample in addition the flux of beryllium-7 neutrinos, which are second only to boron-8 neutrinos in sensitivity to the core temperature.)"[14]

Rutheniums[edit]

This is a piece of native ruthenium from Verkhneivinsk, Neiva river, Sverdlovskaya Oblast', Middle Urals, Urals Region, Russia. Credit: Hudson Institute of Mineralogy.

The piece of native ruthenium in the image on the right contains some iridium. It is from Verkhneivinsk, Neiva river, Sverdlovskaya Oblast', Middle Urals, Urals Region, Russia.

Rhodiums[edit]

Main sources: Chemicals/Rhodiums and Rhodiums
This image of microbreccia contains rhodium-bearing ferroplatinum. Credit: T. A. Gornostaeva, P. M. Kartashov, A. V. Mokhov, and O. A. Bogatikov.

The image on the right contains small particles of native rhodium-bearing ferroplatinum. This sample was obtained from the lunar regolith "by the Luna-16 automatic station".[79]

"Terrestrial iron-free rhodium-bearing platinum with the composition of Pt0.68Rh0.32 in association with platinum-bearing rhodium Rh0.57Pt0.43 [...] was originally discovered in heavy fractions from basic rocks (norite, gabbro, and anorthosite) in the upper zone of the layered Stillwater intrusion (Montana, United States) [2]."[79]

Palladiums[edit]

This is a palladium nugget. Credit: Hudson Institute of Mineralogy.
This piece of native palladium is from the Mednorudyanskoye Cu Deposit, Nizhnii Tagil, Sverdlovskaya Oblast', Middle Urals, Urals Region, Russia. Credit: Hudson Institute of Mineralogy.

"Natural Palladium [like the nugget shown on the right] always contains some Platinum."[80]

This palladium nugget is from Bom Sucesso Creek, Serro, Minas Gerais, Brazil.

"(Pd,Cu) alloys, some with the approximate composition PdCu4, are reported by Kapsiotis et al. (2010)."[80]

The piece of native palladium [image on the left] from the Mednorudyanskoye Cu Deposit, Nizhnii Tagil, Sverdlovskaya Oblast', Middle Urals, Urals Region, Russia, probably contains some copper.

Silvers[edit]

Main sources: Chemicals/Silvers and Silvers
These specimens are some of the most easily recognizable, dramatic and highly sought after silver specimens from the Western Hemisphere. Credit: Robert Lavinsky.
Native silver is on calcite from Kongsberg, Norway. Credit: Aram Dulyan.

Native silver does occur as cubic, octahedral, or dodecahedral crystals; "also elongated, arborescent, reticulated, or as thin to thick wires."[81]

Cadmiums[edit]

Main sources: Chemicals/Cadmiums and Cadmiums

Indiums[edit]

Main sources: Chemicals/Indiums and Indiums
These pieces of native indium are from Eastern Transbaikal, Russia. Credit: Michael Scott.

On the right are microprobe fragments of native indium from Eastern Transbaikal, Russia. The electron microprobe confirms that indium is the only component of the metallic phase.

Tins[edit]

Main sources: Chemicals/Tins and Tins
This small piece of native tin is from the Badiko District, Bauchi State, Nigeria. Credit: Robert Lavinsky.
This is native tin from a porphyry copper deposit in the Bingham Deposit, Utah, USA. Credit: Alison Roberts.

Native tin such as in the images on the right occurs in two crystal forms: α-Sn (cubic) and β-Sn (tetragonal).[81]

Antimonies[edit]

This is massive antimony with oxidation products from Arechuybo, Mexico. Credit: Aram Dulyan at the Natural History Museum, London.
The native antimony crystals, lustrous and nicely striated in part, range up to 0.5 cm in size. Credit: Robert Lavinsky.

Native antimony such as occurs in the rock on the upper right with its various oxidation products is crystalline in the hexagonal system.

The second image shows hexagonal crystals with metallic luster.

Telluriums[edit]

This is a native tellurium crystal from the Emperor Mine, Vatukoula, Tavua Gold Field, Viti Levu, Fiji. Credit: Robert Stravinsky.

On the right is an example of native tellurium from the Emperor Mine, Vatukoula, Tavua Gold Field, Viti Levu, Fiji.

Iodines[edit]

Main sources: Chemicals/Iodines and Iodines
Here is gaseous iodine. Credit: Matias Molnar, Laboratorio Quimica Inorganica II - UBA, Argentina.
This shows solid iodine crystals. Credit: LHcheM.

Subject to atmospheric pressure and temperature, iodine can be gaseous, liquid, or solid.

Xenons[edit]

Main sources: Chemicals/Xenons and Xenons
Spectrum = gas discharge tube: the noble gas: xenon Xe. Used with 1,8kV, 18mA, 35kHz. ≈8" length. Credit: Alchemist-hp.
This image of a xenon ion engine, photographed through a port of the vacuum chamber where it was being tested at NASA's Jet Propulsion Laboratory, shows the faint blue glow of charged atoms being emitted from the engine. Credit: NASA.

Xenon is a heavy, gaseous chemical element of the noble gases group.

Caesiums[edit]

Main sources: Chemicals/Rubidiums and Rubidiums
Temperature-pressure diagram for caesium, formerly known as "cesium". Credit: David A. Young, ERDA.

As the temperature-pressure diagram on the left shows, caesium (formerly cesium) is bcc (α-Cs) from room temperature up to melting.

Native caesium does not appear to occur on the surface of the Earth or the Moon.

Bariums[edit]

Main sources: Chemicals/Bariums and Bariums
This is a pressure-temperature phase diagram for barium. Credit: David A. Young, ERDA.

Barium is bcc (α-Ba) at room temperature as the phase diagram on the left indicates. It does change to an hcp structure at high pressures and temperatures.

Native barium is not known to occur on the surface of the Earth.

Hafniums[edit]

Main sources: Chemicals/Hafniums and Hafniums
This is an iron-hafnium phase diagram. Credit: H. Okamoto.

Note in the iron-hafnium phase diagram on the left that hafnium occurs in two phases: hcp (α-Hf) at lower temperatures and bcc (β-Hf) at higher temperatures up to melting.

Tantalums[edit]

Main sources: Chemicals/Tantalums and Tantalums
This is a piece of native tantalum from Kvanefjeld Mountain, Kuannersuit Plateau, Ilímaussaq complex, Narsaq, Kujalleq, Greenland. Credit: V.V. Seredin.
This is a National Bureau of Standards phase diagram for Fe-Ta. Credit: L.J. Swartzendruber and E. Paul.

On the right is a scanning electron micrograph of a piece of native tantalum from Kvanefjeld Mountain, Kuannersuit Plateau, Ilímaussaq complex, Narsaq, Kujalleq, Greenland.

The iron-tantalum phase diagram on the left shows the bcc (α-Ta) phase from lower temperatures through and up to melting.

Tungstens[edit]

Main sources: Chemicals/Tungstens and Tungstens
The small, bright crystalline mass on the right of this electron micrograph is native tungsten. Credit: Andrei V. Mokhov.
This is an iron-tungsten phase diagram. Credit: Satyendra.

In the scanning electron micrograph on the right is a bright grain, or crystalline mass, of native tungsten. The sample is a fragment of lunar silicate glass from the Luna 24 landing site, Mare Crisium, The Moon. The fragment is bright in backscattered electrons.

The iron-tungsten phase diagram on the left shows that the bcc phase of tungsten (α-W) occurs from lower temperatures on up to the melting temperature.

Rheniums[edit]

Main sources: Chemicals/Rheniums and Rheniums
This is an image of the first find of native rhenium in the transitional clay layer at the Cretaceous/Paleogene boundary in the Gams Section. Credit: A. F. Grachev, S. E. Borisovsky, and A. V. Grigor’eva.

"Native rhenium was first discovered in the Earth's crust in wolframites from a rare metal deposit in the Transbaikal region [1]. [...] The study of the lunar regolith from two sites revealed native rhenium particles with different morphological features: irregular dense particles from Mare Fecunditatis and spheroidal particles from Mare Crisium. The origin of particles (less than 10 µm in size) is assigned to exhalative processes [2]. Among the extraterrestrial objects, native rhenium was found in Ni-iron and silicates from the Allende meteorite [3]."[82]

Osmiums[edit]

Main sources: Chemicals/Osmiums and Osmiums
A crystal of native osmium from Nishni Tagil, Ural, Russia, is shown. Credit: Thomas Witzke.

The crystal of native osmium shown on the right is about 2 mm across.

Iridiums[edit]

Main sources: Chemicals/Iridiums and Iridiums
The image is of a cubic crystal of native iridium. Credit: Norman King.

Native iridium such as the small cubic crystal shown in the image on the right is rare.

Platinums[edit]

Main sources: Chemicals/Platinums and Platinums
This is a native platinum nugget, locality Kondyor mine, Khabarovsk Krai, Russia. Credit: Alchemist-hp.

Platinum can also occur as nuggets such as the one imaged on the right from Russia.

Golds[edit]

Main sources: Chemicals/Golds and Golds
This gold nugget (placer gold) is 9.5 mm across at its widest. Credit: James St. John.

Gold (Au) is the most prestigious metal known, but it's not the most valuable. Gold is the only metal that has a deep, rich, metallic yellow color. Almost all other metals are silvery-colored. Gold is very rare in crustal rocks - it averages about 5 ppb (parts per billion). Where gold has been concentrated, it occurs as wires, dendritic crystals, twisted sheets, octahedral crystals, and variably-shaped nuggets. It most commonly occurs in hydrothermal quartz veins, disseminated in some contact- & hydrothermal-metamorphic rocks, and in placer deposits. Placers are concentrations of heavy minerals in stream gravels or in cracks on bedrock-floored streams. Gold has a high specific gravity (about 19), so it easily accumulates in placer deposits. Its high density allows prospectors to readily collect placer gold by panning.

Mercuries[edit]

Main sources: Chemicals/Mercuries and Mercuries
This is a visible emission spectrum of mercury (Hg). Credit: teravolt.
The image shows liquid mercury being pour at room temperature and pressure. Credit: Bionerd.
Spectrum = gas discharge tube filled with mercury Hg vapor, used with 1.8 kV, 18 mA, 35 kHz. ≈8" length. Credit: Alchemist-hp.

"The green mercury line λ 5461 appears to be quite unique in the possession of its satellites."[51]

There are "telluric mercury lines".[83]

There are an additional pair of lines for mercury, one at 496.03 nm in the green and the second at 491.6 nm in the cyan.[84]

As the spectrum of mercury (Hg) indicates, it has lines in the violet.

The metallic element mercury is a liquid at room temperature and pressure as shown in the image on the right.

Def. a naturally occurring, silvery-colored, metallic liquid, composed primarily of the chemical element mercury, is called mercury, or native mercury.

"Abundant cinnabar (HgS) mineralization is associated with the Pinchi Fault in central British Columbia. [...] The mercury content of till (a sediment type directly deposited by glaciers) in the area of this fault is primarily controlled by the occurrence of cinnabar mineralization in bedrock an the direction of ice flow. Cinnabar-bearing bedrock was eroded by glaciers, transported in the direction of ice flow, and deposited "down-ice" from its source."[60]

Thalliums[edit]

Main sources: Chemicals/Thalliums and Thalliums

There is a green thallium line that shows up in arc spectra using "two to eight amperes at 120 volts, usually between ordinary arc carbons."[51]

Leads[edit]

Main sources: Chemicals/Leads and Leads
Lead spectrum is for 400 nm - 700 nm. Credit: McZusatz.{{free media}}
This is a piece of native lead. Credit: Rob Lavinsky.{{free media}}
A piece of lead, cut through, is silvery for a short time, before the surface oxidizes. Credit: Hi-Res Images of Chemical Elements.{{free media}}

The piece of native lead on the right shows a relatively sharp, and well-formed cuboctahedron of Lead at the top of the specimen, which is associated with elongated crystals on the base and back.

Its source locality is Långban, Filipstad, Värmland, Sweden.

A fresh surface of high purity lead on the left is silvery in appearance.

Radons[edit]

Main sources: Chemicals/Radons and Radons

Radon is one of the noble gases.

Franciums[edit]

Main sources: Chemicals/Franciums and Franciums

Francium is bcc at room temperature.

Radiums[edit]

Main sources: Chemicals/Radiums and Radiums

"Solid radium is bcc at room temperature. Radium melts at 973 K.63"[85]

Thoriums[edit]

Main sources: Chemicals/Thoriums and Thoriums
Thorium sample (99.9 % = 3N) is a thin sheet under argon in a glass ampoule, ca. 0.1 g. Credit: Alchemist-hp.
This diagram shows a face-centered cubic lattice. Credit: Daniel Mayer and DrBob.

Def. a chemical element (symbol Th) with atomic number 90 is called thorium.

Thorium is a silvery, radioactive, metallic element. At room temperature and pressure, thorium crystallizes into a face-centered cubic lattice, where one thorium atom occupies each location of a black sphere in the diagram on the left.

Neptuniums[edit]

This mineral, Aeschynite, probably contains on the order of a few atoms of neptunium at any one time, as part of the complex decay chain of the uranium that makes up a much larger fraction of the sample. Credit: Theodore Gray.

The image at the top of the page shows a rock with the mineral Aeschynite approximately centered above the biotite mica. Aeschynite "probably contains on the order of a few atoms of neptunium at any one time, as part of the complex decay chain of the uranium that makes up a much larger fraction of the sample."[86]

Plutoniums[edit]

This is a sample of the naturally occurring mineral muromontite. Credit: eBay seller rubbleshop.

"The sample [on the right] representing plutonium is the naturally occurring mineral muromontite, which is a mixture of uranium and beryllium. [The] alpha particles from the decay of uranium are captured by the beryllium atoms, which in turn release neutrons. [...] In the case of this sample, [...] the neutrons are in turn re-captured by the uranium, which then undergoes further decay and is transformed into plutonium. The result is that this mineral contains the highest known naturally occurring concentration of plutonium."[87]

Americiums[edit]

Sorption of americium at trace levels has been detected on a clay mineral.[88]

Curiums[edit]

Main sources: Chemicals/Curiums and Curiums

"Curium is a radioactive transuranic element that has only been produced in nuclear reactors. It is possible that some curium and other transuranic elements were created in the natural nuclear reactor in Oklo, Gabon."[89]

Berkeliums[edit]

Like americium and curium it "is possible that some berkelium and other transuranic elements were created in the natural nuclear reactor in Oklo, Gabon."[90]

Roentgeniums[edit]

"Based on the observation of the long-lived isotopes of roentgenium, 261Rg and 265Rg (Z = 111, t1/2 ≥ 108 y) in natural Au, an experiment was performed to enrich Rg in 99.999% Au. 16 mg of Au were heated in vacuum for two weeks at a temperature of 1127°C (63°C above the melting point of Au). The content of 197Au and 261Rg in the residue was studied with high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The residue of Au was 3 × 10−6 of its original quantity. The recovery of Rg was a few percent. The abundance of Rg compared to Au in the enriched solution was about 2 × 10−6, which is a three to four orders of magnitude enrichment."[91]

Ions[edit]

Main sources: Plasmas/Ions and Ions
This is a colour composite image of RCW120. Credit: ESO/APEX/DSS2/ SuperCosmos/ Deharveng(LAM)/ Zavagno(LAM).
A hydrogen atom (center) contains a single proton and a single electron. Removal of the electron gives a cation (left), whereas addition of an electron gives an anion (right). Credit: Jkwchui.

The image at right is a colour "composite image of RCW120. It reveals how an expanding bubble of ionised gas about ten light-years across is causing the surrounding material to collapse into dense clumps where new stars are then formed. The 870-micron submillimetre-wavelength data were taken with the LABOCA camera on the 12-m Atacama Pathfinder Experiment (APEX) telescope. Here, the submillimetre emission is shown as the blue clouds surrounding the reddish glow of the ionised gas (shown with data from the SuperCosmos H-alpha survey). The image also contains data from the Second Generation Digitized Sky Survey (I-band shown in blue, R-band shown in red)."[92]

An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge.

The hydrogen anion (shown in the diagram at right), with its loosely held two-electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of the cation. Hydrogen forms the only cation that has no electrons, but even cations that (unlike hydrogen) retain one or more electrons, are smaller than the neutral atoms or molecules from which they are derived.

"In the second dominant group of ions we generally see more discrepancies in the model and the HIS data".[93]

Nitrates[edit]

Nitrate (NO3-) concentrations in the [glacial and snowpack meltwaters] GSF lakes were 1-2 orders of magnitude higher than in [snowpack melt] SF lakes. Although nitrogen (N) limitation is common in alpine lakes, algal biomass was lower in highly N-enriched GSF lakes than in the N-poor SF lakes."[94]

Molecules[edit]

Main sources: Chemicals/Molecules and Molecules
This image from the APEX telescope is part of the Taurus Molecular Cloud. Credit: ESO/APEX (MPIfR/ESO/OSO)/A. Hacar et al./Digitized Sky Survey 2. Acknowledgment: Davide De Martin.

"Using the Submillimeter Array, a set of eight radiotelescopes atop Mauna Kea in Hawaii, [it was] found that G0.253+0.016 possesses very few ultra-dense nuggets that could collapse to form stars."[95]

"This image [at right] from the APEX telescope, of part of the Taurus Molecular Cloud, shows a sinuous filament of cosmic dust more than ten light-years long. In it, newborn stars are hidden, and dense clouds of gas are on the verge of collapsing to form yet more stars. The cosmic dust grains are so cold that observations at submillimetre wavelengths, such as these made by the LABOCA camera on APEX, are needed to detect their faint glow. This image shows two regions in the cloud: the upper-right part of the filament shown here is Barnard 211, while the lower-left part is Barnard 213."[96]

"The submillimetre-wavelength observations from the LABOCA camera on APEX, which reveal the heat glow of the cosmic dust grains, are shown here in orange tones. They are superimposed on a visible-light image of the region, which shows the rich background of stars. The bright star above the filament is φ Tauri."[96]

"The ω-hydroxymonocarboxylates represented the dominant group with a contribution higher than one quarter of the total."[97]

Iron hydride[edit]

"Carroll and McCormack (1972) in Dublin reported complex spectra in the blue and green wavelength regions of both FeH and FeD".[98]

"Carroll et al. (1976) detected a number of coincidences between laboratory lines of FeH and weak unidentified solar lines, again in the blue and green wavelength region, in addition to the infrared."[99]

Cyanides[edit]

"The CN radical through emission in its Violet system bands has a long-established presence in comets."[100]

Acids[edit]

Main sources: Chemicals/Acids and Acids

Notation: let the symbol HA stand for humic acid.

"HAs have been the main object of study in the investigated soils primarily because, from an ecological point of view, this is the most stable, though not always dominant group of substances."[101]

An organic acid is an organic compound with acidic properties. The most common organic acids are the carboxylic acids, whose acidity is associated with their carboxyl group –COOH.

"That good correlation can be obtained if one focuses attention on the dominant group can be nicely illustrated with the benzoic acids."[102]

Bases[edit]

Main sources: Chemicals/Bases and Bases

Compounds[edit]

Main sources: Chemicals/Compounds and Compounds
The HIFI spectrum of the Orion Nebula is superimposed on a Spitzer image of Orion. Credit: ESA, HEXOS and the HIFI Consortium.

"The HIFI spectrum of the Orion Nebula, superimposed on a Spitzer image of Orion. A characteristic feature is the spectral richness: among the organic molecules identified in this spectrum are water, carbon monoxide, formaldehyde, methanol, dimethyl ether, hydrogen cyanide, sulfur oxide, sulfur dioxide and their isotope analogues. It is expected that new molecules will also be identified. This spectrum is the first glimpse at the spectral richness of regions of star and planet formation. It harbors the promise of a deep understanding of the chemistry of space once the complete spectral surveys are available."[103]

"This HIFI spectrum was obtained for the Herschel HEXOS Key Program - a scientific investigation using the Herschel HIFI and PACS instruments to perform full line surveys of five sources in the Orion and Sagittarius B2 molecular clouds."[103]

Oxidanes[edit]

Main source: Chemicals/Oxidanes
Mineral water is being poured from a bottle into a glass. Credit: Walter J. Pilsak.
Impact from a water drop to water causes an upward "rebound" jet surrounded by circular capillary waves. Credit: Fir0002/Flagstaffotos.

"Hill Formula: H2O. Molecular Weight: 18.02 g/mol. CAS registry number(s): 7732-18-5. Substance name(s): water; Wasser; Wasserstoffoxid; Eis; Wasserdampf; Oxidane; R 718; R-718; Ice; Wasser."[104]

"The major atmospheric gases on Earth, Venus, and Mars were probably CO2, H2O, and N2. [The ions from the upper parts of an atmosphere] are often suprathermal, and their interactions can produce suprathermal neutral atoms as well [The] ionopause [...] separates the bound ionosphere from an outer region in which the solar wind is diverted and flows around and past the planet. This region still contains some neutral gas, and if such atoms are ionized by solar photons or electron impact, they are swept up in the flow."[105]

"Isotopic exchange between ice and water is found to take place in temperate glaciers. This exchange causes homogenization of deuterium in snow during summer thaws, together with a general increase in deuterium concentration."[106]

"Oxygen-isotope analyses of ice and firn from the Saskatchewan Glacier, Canada, and the Malaspina Glacier, Alaska, show that variations in ratios are likely to be of considerable value in glaciological research."[29]

The image on the right demonstrates that this substance's constituent parts are sticking together but not crystallizing as it flows from a bottle into a glass.

Def. a clear liquid having the chemical formula H2O, required by all forms of life on Earth is called water.

Def. of water from the metadefinition of a clear liquid:

  1. a clear flowing substance
  2. keeping or retaining no shape or definite shape
a. except that determined by the containing receptacle
3. composed of H2O molecules
a. not tending to separate from one another like those of a gas
b. readily changing relative position

is called water.

In the image on the right impact from a water drop to contained but open water causes an upward "rebound" jet surrounded by circular capillary waves.

Hydrogen fluoride[edit]

"[T]he detection of absorption by interstellar hydrogen fluoride (HF) [in the submillimeter band occurs] along the sight line to the submillimeter continuum sources W49N and W51."[107]

"[T]he 1232.4762 GHz J = 1-0 HF transition [has been observed] in the upper sideband of the band 5a receiver."[107]

"HF is the dominant reservoir of fluorine wherever the interstellar H2/atomic H ratio exceeds ~ 1; the unusual behavior of fluorine is explained by its unique thermochemistry, F being the only atom in the periodic table that can react exothermically with H2 to form a hydride."[107]

The observations "toward W49N and W51 [occurred] on 2010 March 22 ... The observations were carried out at three different local oscillator (LO) tunings in order to securely identify the HF line toward both sight lines. The dual beam switch mode (DBS) was used with a reference position located 3' on either side of the source position along an East-West axis. We centered the telescope beam at α =19h10m13.2s, δ = 09°06'12.0" for W49N and α = 19h23m43.9s, δ = 14°30'30.5" for W51 (J2000.0). The total on-source integration time amounts to 222s on each source using the Wide Band Spectrometer (WBS) that offers a spectral resolution of 1.1 MHz (~0.3 km s-1 at 1232 GHz)."[107]

Hydrogen chloride[edit]

"[T]he first detection of chloronium, H2Cl+, in the interstellar medium, [occurred on March 1 and March 23, 2010,] using the HIFI instrument aboard the Herschel Space Observatory. The 212 − 101 lines of ortho-H235Cl+ and ortho-H237Cl+ are detected in absorption towards NGC 6334I, and the 111 − 000 transition of para-H235Cl+ is detected in absorption towards NGC 6334I and Sgr B2(S)."[108]

Carbon monoxide[edit]

The ALMA observations — shown here in red, pink and yellow — were tuned to detect carbon monoxide molecules. Credit: ALMA (ESO/NAOJ/NRAO). Visible light image: the NASA/ESA Hubble Space Telescope.

"The Antennae Galaxies (also known as NGC 4038 and 4039) are a pair of distorted colliding spiral galaxies about 70 million light-years away, in the constellation of Corvus (The Crow). This view combines ALMA observations, made in two different wavelength ranges during the observatory’s early testing phase, with visible-light observations from the NASA/ESA Hubble Space Telescope."[109]

"The Hubble image is the sharpest view of this object ever taken and serves as the ultimate benchmark in terms of resolution. ALMA observes at much longer wavelengths which makes it much harder to obtain comparably sharp images. However, when the full ALMA array is completed its vision will be up to ten times sharper than Hubble."[109]

"Most of the ALMA test observations used to create this image were made using only twelve antennas working together — far fewer than will be used for the first science observations — and much closer together as well. Both of these factors make the new image just a taster of what is to come. As the observatory grows, the sharpness, speed, and quality of its observations will increase dramatically as more antennas become available and the array grows in size. This is nevertheless the best submillimetre-wavelength image ever taken of the Antennae Galaxies and opens a new window on the submillimetre Universe."[109]

"While visible light — shown here mainly in blue — reveals the newborn stars in the galaxies, ALMA’s view shows us something that cannot be seen at those wavelengths: the clouds of dense cold gas from which new stars form. The ALMA observations — shown here in red, pink and yellow — were made at specific wavelengths of millimetre and submillimetre light (ALMA bands 3 and 7), tuned to detect carbon monoxide molecules in the otherwise invisible hydrogen clouds, where new stars are forming."[109]

"Massive concentrations of gas are found not only in the hearts of the two galaxies but also in the chaotic region where they are colliding. Here, the total amount of gas is billions of times the mass of the Sun — a rich reservoir of material for future generations of stars."[109]

Zinc selenides[edit]

"ZnSe appears as an attractive material to blue and near UV optoelectronics."[110]

Inorganics[edit]

Def. any chemical not containing carbon atoms or containing carbon atoms ionically bound to other atoms is called an inorganic, or inorganic compound, or inorganic others by analogy.

Usage notes

  • By convention they also include the carbides, carbonates, carbon monoxide and carbon dioxide; carbon disulphide is debatable.

"The behavior of both moieties could be successfully described by the L component of the TLS analysis, with the T and S components having negligible magnitudes, indicating that libration about the central atom was the dominant group motion for both species."[111]

"The sterically dominant group in the O,NTf chiral ligand is the SO 2 moiety, as one oxygen protrudes into the open quadrant created by one of the back pointing pseudoaxial P-phenyl substituents."[112]

"Both of the emission spectra present the characteristic emission bands originating from the transition 5D4 → 7FJ (J=6, 5, 4, 3), with the transition 5D4 → 7F5 green emission as the dominant group.[113]

Organics[edit]

Main sources: Chemicals/Organics and Organics
Benzyl acetate has an ester functional group (in red), an acetyl moiety (circled with green) and a benzyloxy moiety (circled with orange). Other divisions can be made. Credit: Pen1234567.

Notation: let the symbol PE stand for polyethylene.

"Finally, there is a dominant group (PE) that is still growing on the market."[114]

"Phosphomonoesters are the dominant group of organic phosphorus compounds in most soils and comprise 16%–55% of total soil P."[115]

"In sediments, total PCT concentrations expressed as A5442 equivalents ranged from 22 to 100 μg/kg of wet weight, with hepta-CTs as the dominant group of congeners."[116]

"The four model compounds selected represent pyridinic and CN nitrogen groups, pyridinic nitrogen because this group has been observed to be a dominant group and CN because of the indirect observation of HCN formation."[117]

"In contrast, with hydrogen as the primary electron donor, homoacetogens became the dominant group in hydrogen utilization with their advantageous kinetic properties."[118]

"[T]he dominant group is the same in each case and the subsidiary group is changed only by the substitution of acetyl for methyl at the oxygen atom."[119]

"It appears to us that the only interpretation that can be placed upon the facts as they are now known to us is that the acceptor is a radicle which is very closely allied to, if not identical with, a dominant group in the hydrolyte."[120]

"Volatile organic compounds (VOCs) are organic chemicals that have a high vapor pressure at ordinary, room-temperature conditions. Their high vapor pressure results from a low boiling point, which causes large numbers of molecules to evaporate or sublimate from the liquid or solid form of the compound and enter the surrounding air."[121]

Methanes[edit]

Main sources: Chemicals/Methanes and Methanes
The diagram describes how methane leaks from sea beds. Credit: Katey Walter, University of Alaska at Fairbanks.
Methane bubbles are trapped in lake ice in Siberia in early autumn. Credit: Katey Walter, AP/Nature.
This is a liquid methane pumping station. Credit: hollander.nl.
This rocket engine uses liquid methane to produce a 7,500-pound thrust. Credit: NASA.

The diagram at the right describes how methane (CH4) leaks from sea beds.

"Methane is far more powerful in trapping heat, but only lasts about a decade before it dissipates into carbon dioxide and other chemicals. Carbon dioxide traps heat for about a century."[122]

"Most of the yedoma is in little-studied areas of northern and eastern Siberia. What makes that permafrost special is that much of it lies under lakes; the carbon below gets released as methane. Carbon beneath dry permafrost is released as carbon dioxide."[122]

"The big methane or carbon dioxide release hasn’t started yet, but it’s coming."[123]

"Methane trapped in a special type of permafrost [in the image at the right] is bubbling up at rate five times faster than originally measured [...]."[124]

"Care for the environment is becoming more and more of an issue in business today, also in the transport sector and liquid methane gas is a good alternative for diesel fuel."[125]

"Liquid methane gas and diesel fuel are used in combination. When the liquid methane gas and the diesel fuel are mixed in a proportion of 75-25 a truck can run 500 to 1000 km. depending on the driving circumstances."[125]

"The use of the liquid gas depends on economies that are made by using it. The gas is cheaper. One kilo (liquid methane is expressed in kilos) costs less than one litre of diesel and contains 35% more energy. A truck running on it, is far more expensive though. A normal truck costs 100.000 Euro, a truck running on liquid gas, 35.000 Euro more. And also the refuelling possibilities are restricted. Some more facilities are planned though."[125]

"Rocket engines aren't exactly synonymous with liquid methane, but NASA's latest project shows just what this natural gas is capable of -- produces 7,500-pound thrust in this case. Best of all, "you don't have to put on a HAZMAT suit to handle it like fuels used on many space vehicles.""[126]

Alcohols[edit]

These are different alcohol-containing beverages. Credit: Humberto.

Def. any of a class of organic compounds (such as ethanol) containing a hydroxyl functional group (-OH) is called an alcohol.

"As such alcohols became the dominant group of volatiles in the overripe mango, the relative concentrations of other groups of compounds were, of course, correspondingly reduced."[127]

Ethanols[edit]

Def. of ethanol from the metadefinition of a clear liquid:

  1. a clear flowing substance
  2. keeping or retaining no shape or definite shape
a. except that determined by the containing receptacle
3. composed of C2H5OH molecules
a. not tending to separate from one another like those of a gas
b. readily changing relative position

is called ethanol.

Functional groups[edit]

"Various oxygen functionalities include carboxyl (−COOH), the dominant group, and phenolic and/or enolic −OH, alcoholic −OH, and carbonyl (−CO)."[128]

In organic chemistry, functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. The same functional group will undergo the same or similar chemical reaction(s) regardless of the size of the molecule it is a part of.[129] However, its relative reactivity can be modified by nearby functional groups. "In diffuse clouds the dominant group appears to be -CH3."[130]

Bio-organics[edit]

Neurochemicals include transmitters, peptides, proteins, lipids, sugars, and nucleic acids.

Fatty acids[edit]

"Overall, polyunsaturated fatty acids were the dominant group of fatty acids (Table 2), except at Station 6 where saturated fatty acids also dominated the fatty acid pool."[131]

Dopamine-β-Hydroxylases[edit]

"Plasma levels of activity in the autosomal dominant group (1700 ± 90 U) were higher than those in the control (850 ± 60 U) or the autosomal recessive group (660 ± 70 U) (p less than 0.001)."[132]

Anthocyanins[edit]

"According to their composition, the Japanese cultivars can be categorized into two groups on the basis of the shade of color and the peonidin/cyanidin (pn/cy) ratio: cyanidin types (pn/cy < 1.0) with a greater degree of blueness (blue dominant group) and peonidin types (pn/cy > 1.0) with a greater degree of redness (red dominant group) (9, 16)."[133]

"On the basis of the calculated peonidin/cyanidin ratio (0.10) this cultivar belongs to the blue dominant group (“cyanidin-type”)."[133]

Iodopsins[edit]

Iodopsins are the photoreceptor proteins found in the cone cells of the [human] retina that are the basis of color vision. Iodopsins are very close analogs of the visual purple rhodopsin [R] that is used in night vision. Iodopsins consist of a protein called photopsin and a bound chromophore, retinal.

In humans there are three different iodopsins (rhodopsin analogs) that form the protein-pigment complexes photopsin I, II, and III. They are called erythrolabe, chlorolabe, and cyanolabe, respectively.[134] These photopsins have absorption maxima for yellowish-green (photopsin I), green (photopsin II), and bluish-violet light (photopsin III).

Alloys[edit]

Main sources: Chemicals/Alloys and Alloys

"The broad, 60 < FWHM < 100 nm, featureless luminescence band known as extended red emission (ERE) is seen in such diverse dusty astrophysical environments as reflection nebulae17, planetary nebulae3, HII regions (Orion)12, a Nova11, Galactic cirrus14, a dark nebula7, Galaxies8,6 and the diffuse interstellar medium (ISM)4. The band is confined between 540-950 nm, but the wavelength of peak emission varies from environment to environment, even within a given object. ... the wavelength of peak emission is longer and the efficiency of the luminescence is lower, the harder and denser the illuminating radiation field is13. These general characteristics of ERE constrain the photoluminescence (PL) band and efficiency for laboratory analysis of dust analog materials."[135]

"The PL efficiencies measured for HAC and Si-HAC alloys are consistent with dust estimates for reflection nebulae and planetary nebulae, but exhibit substantial photoluminescence below 540 nm which is not observed in astrophysical environments."[135]

"Optical constants measured at normal incidence for iron (Bolotin et al., 1969) and for iron-nickel alloys (Sasovskaya and Noskov, 1974) also predict a red-sloped spectrum."[136]

"Grain size varies from 98 to 530 lm with an average of *150 lm. Minor [elements] oxidation [from an iron–nickel–chromium–cobalt–phosphorus alloy] is evidenced by the presence of a light brown and blue surface layer composed of very fine-grained (<1 lm) crystals on the surface."[137] "[T]he oxidation of minor elements in metallic alloys in the early solar system" is indicated to possess at instances a blue surface layer.[137]

Mineraloids[edit]

Def. a substance that resembles a mineral but does not exhibit crystallinity is called a mineraloid.

Petroleums[edit]

This is a natural oil (petroleum) seep near Korňa, Kysucké Beskydy, Western Carpathians, Slovakia. Credit: Branork.

Def. a flammable liquid ranging in color from clear to very dark brown and black, consisting mainly of hydrocarbons, occurring naturally in deposits under the Earth's surface is called a petroleum.

Minerals[edit]

Main source: Minerals

"A mineral is a naturally occurring homogeneous solid, inorganically formed, with a definite chemical composition and an ordered atomic arrangement. Ice is naturally occurring, given a temperature below 0 degrees Celsius (32 degrees Fahrenheit). It is homogenous (of one material), formed inorganically, and has an ordered atomic structure. Ice has a definite chemical composition (H20), with hydrogen and oxygen atoms bonding in a specific manner."[138]

Materials[edit]

Main sources: Chemicals/Materials and Materials
This slice through the new ALMA data reveals the shell around the star. Credit: ALMA (ESO/NAOJ/NRAO).
This is a photograph in natural light of the vertically oriented pores in congelation ice. Credit: Ted Maksym, United States Naval Academy.

"Calculations were made using the wavelength-dependent complex refractive indices of silicate (Draine 1985), glassy carbon (Edoh 1983), and Tholin (Khare et al. 1984). [...] these materials were chosen as broadly representative of the types of matter thought to be present in comet dust."[139]

"Observations using the Atacama Large Millimeter/submillimeter Array (ALMA) have revealed an unexpected spiral structure in the material around the old star R Sculptoris. This feature has never been seen before and is probably caused by a hidden companion star orbiting the star. This slice through the new ALMA data reveals the shell around the star, which shows up as the outer circular ring, as well as a very clear spiral structure in the inner material."[140] The image band is centered at 870 µm.

Def. "an advanced form of new ice that forms as a stable sheet with a smooth bottom surface"[138] is called congelation ice.

At the right is a "photograph in natural light of the vertically oriented pores in congelation ice."[138]

Shelters[edit]

The image shows the protective dome or shelter for the Caltech Submillimeter Observatory at the Mauna Kea Observatory. Credit: Rnt20 (Bob Tubbs).

The image at right shows the protective dome or shelter for the Caltech Submillimeter Observatory at the Mauna Kea Observatory.

See also[edit]

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