Reactions of ionic halides

From Wikiversity

Contents 1 Detecting ionic halides 1.1 Aqueous halides with silver nitrate 1.2 Aqueous halides with ammonia solutions 2 Solid ionic halides and concentrated sulphuric acid 2.1 Sodium fluoride 2.2 Sodium chloride 2.3 Sodium bromide 2.4 Sodium iodide

[edit] Detecting ionic halides

• Most halides are soluble

[edit] Aqueous halides with silver nitrate

• We can detect them in solution by adding silver nitrate solution:
  • We get the corresponding silver halide forming (AgCl, AgBr, AgI) which are insoluble (except for AgFl) so they form a precipitate:

AgFl is soluble; no precipitate formed

AgCl forms a white precipitate

AgBr forms a cream precipitate

AgI forms a yellow precipitate

An easy way to remember the results is that as we move down Group VII of the periodic table, the colours get "darker". So AgFl is colourless because it is completely soluble, AgCl forms a white ppt, AgBr forms a cream ppt, and AgI forms a yellow ppt

[edit] Aqueous halides with ammonia solutions

Distinguishing between white, cream and yellow can be difficult, so a second test can be used to confirm the results.

[edit] Solid ionic halides and concentrated sulphuric acid

Solid ionic halides can be detected by their reactions with conc. sulphuric acid:

• First, the corresponding hydrogen halide is formed
• Then, the differences in the reactions depend on the reducing ability of the hydrogen halide and the moderately strong oxidising ability of concentrated sulphuric acid
• HFl is not a reducing agent but the other hydrogen halides are increasing so

So conc. sulphuric acid:

• does not react with HFl or HCl
• but does oxidise HBr and HI freeing the the halogens
• HBr reduces sulphuric acid to SO₂
• HI (being an even stronger reducing agent) reduces the acid to hydrogen sulphide

[edit] Sodium fluoride

NaF(aq) + H₂SO₄(l) → HF(g) + NaHSO₄(l) No further reaction occurs.

[edit] Sodium chloride

NaCl(aq) + H₂SO₄(l) → HCl(g) + NaHSO₄(l) No further reaction occurs.

[edit] Sodium bromide

• NaBr(aq) + H₂SO₄(l) → HBr(g) + NaHSO₄(l)
• As conc. sulphuric acid is a moderately strong oxidising agent, it oxidises HBr to Br:

2HBr(aq) + H₂SO₄(l) → Br₂(g) + SO₂(g) + 2H₂O(l)

• The aqueous bromide ion from HBr has been oxidised to form bromine:

2Br^- → Br₂ + 2e^-

• The HBr and acid each provide 2H⁺ ions and the electrons from bromine are transferred to the sulphate ion:

4H⁺ + SO₂^2- + 2e^- → SO₂ + 2H₂O

• Adding these two equations together we get:

2HBr(aq) + 2e^- + H₂SO₄(l) → Br₂(g) + 2e^- + SO₂(g) + 2H₂O(l)

The electrons on either side of the equation cancel to give the overall equation for the reaction which is shown above

[edit] Sodium iodide

Here several reactions occur:

• NaI(aq) + H₂SO₄(l) → HI(g) + NaHSO₄(l)

As usual the hydrogen halide is produced (hydrogen iodide in this case)

• Next, two different reactions can occur:
  • The HI is oxidised to I₂, and the sulphuric acid is reduced to sulphur dioxide and water

2HI(aq) + H₂SO₄(l) → I₂(g) + SO₂(g) + 2H₂O(l)

• The HI is oxidised to I₂, but this time the sulphuric acid is reduced to hydrogen sulphide and water

8HI(aq) + H₂SO₄(l) → 4I₂(s) + H₂S(g) + 4H₂O(l)